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Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a Caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8″ x 10″ hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential.

Repeatable measurement of real-world heavy-duty diesel truck emissions requires the use of a chassis dynamometer with a test schedule that reasonably represents actual truck use. A new Heavy Heavy-Duty Diesel Truck (HHDDT) schedule has been created that consists of four modes, termed Idle, Creep, Transient and Cruise. The effect of driving style on emissions from the Transient Mode was studied by driving a 400 hp Mack tractor at 56,000 lbs. test weight in fashions termed “Medium”, “Good”, “Bad”, “Casual” and “Aggressive”. Although there were noticeable differences in the actual speed vs. time trace for these five styles, emissions of the important species oxides of nitrogen (NOx) and particulate matter (PM), varied little with a coefficient of variation (COV) of 5.13% on NOX and 10.68% on PM. Typical NOx values for the HHDDT Transient mode ranged from 19.9 g/mile to 22.75 g/mile. The Transient mode which was the most difficult mode to drive, proved to be repeatable.

When heavy-duty truck emissions rates are expressed in distance-specific units (such as g/mile), average speed and the degree of transient behavior of the vehicle activity can affect the emissions rate. Previous one-dimensional studies have shown some correlation of distance-specific emissions rates between cycles. This paper reviews emissions data sets from the 5-mode CARB Heavy Heavy-Duty Diesel Truck (HHDDT) Schedule, the Heavy Duty Urban Dynamometer Driving Schedule (UDDS) and an inspection and maintenance cycle, known as the AC5080. A heavy-duty chassis dynamometer was used for emissions characterization along with a full-scale dilution tunnel. The vehicle test weights were simulated at 56,000 lbs. Two-dimensional correlations were used to predict the emissions rate on one mode or cycle from the rates of two other modes or cycles.

Increasingly stringent oxides of nitrogen (NOx) and particulate matter (PM) regulations worldwide have prompted considerable activity in developing emission control technology to reduce the emissions of these two constituents from heavy-duty diesel engines. NOx has come under particular scrutiny by regulators in the US and in Europe with the promulgation of very stringent regulation by both the US Environmental Protection Agency (EPA) and the European Union (EU). In response, heavy-duty engine manufacturers are considering Selective Catalytic Reduction (SCR) as a potential NOx reduction option. While SCR performance has been well established through engine dynamometer evaluation under laboratory conditions, there exists little data characterizing SCR performance under real-world operating conditions over time. This project evaluated the field performance of ten SCR units installed on heavy-duty Class 8 highway and refuse trucks.

Selective NOX Recirculation (SNR) involves three main steps in NOX reduction. The first step adsorbs NOX from the exhaust stream, followed by periodic desorption from the aftertreatment medium. The final step passes the desorbed NOX gas into the intake air stream and feeds into the engine. A percentage of the NOX is expected to be decomposed during the combustion process. The motivation for this research was to clarify the reduction of NOX from large stationary engines. The objective of this paper is to report the NOX decomposition phenomenon during the combustion process from three test engines. The results will be used to develop an optimal system for the conversion of NOX with a NOX adsorbtion system. A 1993 Cummins L10G natural gas engine, a 1992 Detroit Diesel series 60 engine and a 13hp Honda gasoline engine were used in the experiments. Commercially available nitric oxide (NO) was injected into the engine intake to mimic the NOX stream from the desorption process.

Emissions from diesel engines, particularly NOx and TPM emissions are harmful to the environment. Reduction of NOx emissions from diesel engines is of increasing concern. In 1998, a novel approach called Selective NOx Recirculation (SNR) was used to reduce NOx emissions in diesel engines. The SNR concept relies on two major parts, one to collect the NOx emissions from the exhaust by an adsorber, and another to decompose NOx using the in-cylinder combustion process by injecting the collected NOx emissions into the intake manifold at an elevated concentration. This paper deals with the destruction rates during the combustion process. A 1992 DDC series 60, 350 hp, 12.7 liter engine was connected to a 500 hp DC dynamometer. A full-scale dilution tunnel and analyzers capable of measuring continuous NOx, CO2, CO, HC, and PM in the exhaust were used.

Understanding the nitric oxide (NO) conversion process plays a major role in optimizing the Selective NOX Recirculation (SNR) technique. SNR has been proven in gasoline and diesel engines, with up to 90% NOX conversion rates being achieved. This technique involves adsorbing NOX from an exhaust stream, then selectively desorbing the NOX into a concentrated NOX stream, which is fed back into the engine's intake, thereby converting a percentage of the concentrated NOX stream into harmless gases. The emphasis of this paper is on the unique chemical kinetic modeling problem that occurs with high concentrations of NOX in the intake air of a spark ignited natural gas engine with SNR. CHEMKIN, a chemical kinetic solver software package, was used to perform the reaction modeling. A closed homogeneous batch reactor model was used to model the fraction of NOX versus time for varying initial conditions and constants.

The effects of fuel composition on emissions levels from compression ignition engines can be profound, and this understanding has led to mandated reductions in both sulfur and aromatic content of automotive diesel fuels. A Navistar T444E (V8, 7.3 liter) engine was installed on an engine dynamometer and subjected to transient emissions measurement using a variety of fuels, namely federal low sulfur pump diesel; California pump diesel; Malaysian Fischer-Tropsch fuel with very low sulfur and aromatic content; various blends of soy-derived biodiesel; a Fischer-Tropsch fuel with very low sulfur and 10% aromatics; and the same Fischer-Tropsch fuel with 10% isobutanol by volume. The biodiesel blends showed their ability to reduce particulate matter, but at the expense of increasing oxides of nitrogen (NOx), following the simple argument that cetane enhancement led to earlier ignition. However, the Fischer-Tropsch fuels showed their ability to reduce all of the regulated emissions.

The emissions reduction benefits of Fischer-Tropsch (FT) diesel fuel have been shown in several recent published studies in both engine testing and in-use vehicle testing. FT diesel fuel shows significant advantages in reducing regulated engine emissions over conventional diesel fuel primarily to: its zero sulfur specification, implying reduced particulate matter (PM) emissions, its relatively lower aromaticity, and its relatively high cetane rating. However, the actual effect of FT diesel formulation on the in-cylinder combustion characteristics of unmodified modern heavy-duty diesel engines is not well documented. As a result, a Navistar T444E (V8, 7.3 liter) engine, instrumented for in-cylinder pressure measurement, was installed on an engine dynamometer and subjected to steady-state emissions measurement using both conventional Federal low sulfur pump diesel and a natural gas-derived FT fuel.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.

Chassis based emissions characterization of heavy-duty vehicles has advanced over the last decade, but the understanding of the effect of test schedule on measured emissions is still poor. However, this is an important issue because the test schedule should closely mimic actual vehicle operation or vocation. A wide variety of test schedules was reviewed and these cycles were classified as cycles or routes and as geometric or realistic. With support from the U.S. Department of Energy Office of Transportation Technologies (DOE/OTT), a GMC box truck with a Caterpillar 3116 engine and a Peterbilt over the road tractor-trailer with a Caterpillar 3406 engine were exercised through a large number of cycles and routes. Test weight for the GMC was 9,980 kg and for the Peterbilt was 19,050 kg. Emissions characterization was performed using a heavy-duty chassis dynamometer, with a full-scale dilution tunnel, analyzers for gaseous emissions, and filters for PM emissions.

Although diesel engines still power most of the heavy-duty transit buses in the United States, many major cities are also operating fleets where a significant percentage of buses is powered by lean-burn natural gas engines. Emissions from these buses are often expressed in distance-specific units of grams per mile (g/mile) or grams per kilometer (g/km), but the driving cycle or route employed during emissions measurement has a strong influence on the reported results. A driving cycle that demands less energy per unit distance than others results in higher fuel economy and lower distance-specific oxides of nitrogen emissions. In addition to energy per unit distance, the degree to which the driving cycle is transient in nature can also affect emissions.

Most transient heavy duty diesel emissions data in the USA have been acquired using the Federal Test Procedure (FTP), a heavy-duty diesel engine transient test schedule described in the US Code of Federal Regulations. The FTP includes both urban and freeway operation and does not provide data separated by driving mode (such as rural, urban, freeway). Recently, a four-mode engine test schedule was created for use in the Advanced Collaborative Emission Study (ACES), and was demonstrated on a 2004 engine equipped with cooled Exhaust Gas Recirculation (EGR). In the present work, the authors examined emissions using these ACES modes (Creep, Cruise, Transient and High-speed Cruise) and the FTP from a Detroit Diesel Corporation (DDC) Series 60 1992 12.7 liter pre-EGR engine. The engine emissions were measured using full exhaust dilution, continuous measurement of gaseous species, and filter-based Particulate Matter (PM) measurement.

Environmental Protection Agency (EPA) emissions standards for on-road heavy-duty diesel engines in 2007 will require the use of diesel particulate filters (DPF) to reach the regulated limit of 0.01g/bhp-hr for particulate matter. The inorganic portion of the particulate matter, referred to as ash, accumulates in the DPF over time with engine operation and periodic cleaning is necessary to remove the buildup. In anticipation of the required cleaning, flow bench testing and modeling were conducted for heavy-duty diesel DPFs to determine the effectiveness of compressed air nozzle cleaning and water cleaning. The result from this work shows that the first 10 minutes of cleaning removes greater than 55% of the filter soot/ash. Water cleaning was investigated and shows that it reduces filter pressure drop when repeated air cleaning was incapable of further reducing the pressure drop.